Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Carbon Disulfide → HCID 13392986, 화합물
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Carbon Disulfide | HCID 6348 | — |
| 반응물 | 4-Nitrobenzyl chloride | HCID 7482 | — |
| 반응물 | Triethylamine | HCID 8471 | — |
| 반응물 | HCID 13375505 | HCID 13375505 | — |
| 용매 | Methanol | HCID 887 | — |
| 생성물 | HCID 13392986 | HCID 13392986 | — |
반응 단계
In the same manner as described in Example 29 by using (3RS)-3-hydroxymethyl-1,2,3,4-tetrahydro-β-carboline (1.01 g), triethylamine (0.77 ml), CS2 (0.33 ml), 4-nitrobenzyl chloride (1.08 g) and 80% methanol (20 ml), there is prepared the title compound (1.47 g, 71%) as pale yellow needles, m.p. 193°-194° C. (recrystallized from aqueous methanol), NMR (DMSO-d6, δ): 4.79 (s, 2H, ##STR14## Mass m/e: 244 (M+ -- ##STR15##
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04612317 |
| 출처 데이터셋 | uspto-grants-1986_09 |
| ORD ID | ord-5cee22d30ba14824abf37ed2a8fe5c68 |
| 출처 메모 | uspto-grants-1986_09 |