HCID 689895, 화합물 → tert-Butyl 2-benzylhydrazinecarboxylate

HRID 650839노트

반응식

HRID 650839 반응식
[C:1]([O:5][C:6]([NH:8][N:9]=[CH:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1)=[O:7])([CH3:4])([CH3:3])[CH3:2].[H][H]>O1CCCC1.[Pd]>[C:1]([O:5][C:6]([NH:8][NH:9][CH2:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1)=[O:7])([CH3:4])([CH3:2])[CH3:3]

참가 물질

5

반응물 2

HCID 689895HCID 689895, 화합물HCID 178418361HCID 178418361, 화합물

생성물 1

HCID 10656659tert-Butyl 2-benzylhydrazinecarboxylate

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 8028Tetrahydrofuran용매

실험 절차

To a solution of N′-benzylidenehydrazinecarboxylic acid tert-butyl ester (2.7 g, 12.3 mmol) in tetrahydrofuran (100 ml) was added 10% palladium on carbon (0.3 g) and the mixture was hydrogenated with 280 ml of hydrogen for 40 min at atmospheric pressure. The mixture was filtered through a plug of celite and the filtrate was concentrated in vacuo to give 2.63 9 of N′-benzylhydrazinecarboxylic acid tert-butyl ester.

후처리

  1. filtrationThe mixture was filtered through a plug of celite
  2. concentrationthe filtrate was concentrated in vacuo

출처 및 근거

ORD 기록
ord-033cf671250c4eaabbf678e836e3365e
출처 데이터셋
uspto-grants-2001_08
특허 번호
US06274584B1

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