참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Methanol | HCID 887 | — |
| 반응물 | 1,4-Dioxane | HCID 31275 | — |
| 반응물 | Diphenyl[2-(trifluoromethyl)phenyl]phosphane | HCID 303893 | — |
| 촉매 | Palladium Chloride | HCID 24290 | — |
| 생성물 | Methyl isobutyrate | HCID 11039 | — |
| 생성물 | Methyl butyrate | HCID 12180 | — |
반응 단계
The autoclave was charged with 0.3 gms of palladium chloride, 5 gms o-trifluoromethylphenyldiphenylphosphine, 10 mls of methanol and 50 ml of p-dioxane. After flushing with nitrogen, the autoclave was pressurized with carbon monoxide to 800 psig and heated to 120 degrees C. with stirring. 10 gms of liquid propylene was added and the reaction continued at 120° C. and 100 psig for 3 hours. The autoclave was then cooled and the reaction fluid analyzed by gas chromatography. A methyl isobutyrate:methyl n-butyrate ratio of 7.1:1 was obtained.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US04612390 |
|---|
| 출처 데이터셋 | uspto-grants-1986_09 |
|---|
| ORD ID | ord-e5490df9d8cf467daca53ea437840a1c |
|---|
| 출처 메모 | uspto-grants-1986_09 |
|---|
