Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1-Dodecanethiol → 3-(Dodecylsulfanyl)butanal
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1-Dodecanethiol | HCID 8195 | — |
| 반응물 | Crotonaldehyde | HCID 447466 | — |
| 용매 | Triethylamine | HCID 8471 | — |
| 생성물 | 3-(Dodecylsulfanyl)butanal | HCID 13005022 | — |
반응 단계
14.02 Grams of crotonaldehyde (0.20 mole) is added dropwise over a 40-minute period at 60° to 65° C. to a solution of 41.2 grams of n-dodecyl mercaptan (0.20 moles) and 0.66 grams of triethylamine after which heating and stirring are continued at 85° C. for 1.5 hours. Analysis of the reaction mixture indicates that the reaction is then substantially complete. The product is isolated as a light yellow liquid by stripping off the volatiles.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04612341 |
| 출처 데이터셋 | uspto-grants-1986_09 |
| ORD ID | ord-fbab261c40194fdd8da010af0aa35152 |
| 출처 메모 | uspto-grants-1986_09 |