Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Ammonia → 1-Amino-1-[4-methylpiperazino]-2-nitroethene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Ammonia | HCID 222 | — |
| 반응물 | 1-Methylpiperazine | HCID 53167 | — |
| 반응물 | 1,1-Bis(methylthio)-2-nitroethylene | HCID 83623 | — |
| 용매 | 1,1,1,2-Tetrachloroethane | HCID 12418 | — |
| 생성물 | 1-Amino-1-[4-methylpiperazino]-2-nitroethene | HCID 70350030 | — |
반응 단계
An amount of 16.5 g of 1,1-bis-(methylthio)-2-nitroethene is dissolved at high temperature in 100 ml of tetrachloroethane, equimolar amounts of methyl-piperazine are added, the mixture is refluxed over 2 hours; the mass is cooled and anhydrous gaseous ammonia is added to it up to saturation.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04613602 |
| 출처 데이터셋 | uspto-grants-1986_09 |
| ORD ID | ord-67ce7d1c8b6e4df0965b3debb666c260 |
| 출처 메모 | uspto-grants-1986_09 |