Carbon Dioxide → Chlorine
반응식
[Cl:1][Cl:2].C(=O)=O.II.[SH:8][C:9]1[N:14]=[CH:13][CH:12]=[CH:11][N:10]=1>C(Cl)(Cl)(Cl)Cl>[Cl:1][Cl:2].[Cl:1][S:8][C:9]1[N:14]=[CH:13][CH:12]=[CH:11][N:10]=1참가 물질
7
실험 절차
A solution of chlorine in CCl4 is prepared by condensing 4.38 ml liquified Cl2 at dry-ice temperature, and then adding 75 ml CCl4 at -10° to it. To this solution at 0° is added two small crystals of iodine, and then 10.0 g 2-mercaptopyrimidine in 35 ml CCl4 dropwise over 1.5 hours. After stirring another hour, the solvent, excess Cl2 and HCl are evaporated in vacuo, leaving 5.I as residue.
후처리
- customthe solvent, excess Cl2 and HCl are evaporated in vacuo
출처 및 근거
- ORD 기록
- ord-34dfa9135ab34d7ca7dca83c07bd4630
- 출처 데이터셋
- uspto-grants-1987_06
- 특허 번호
- US04670470
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