Sulfuryl chloride → HCID 13382702, 화합물

HRID 653070노트

반응식

HRID 653070 반응식
[C:1]1([S:7][CH2:8][CH2:9][CH2:10][C:11]#[N:12])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.S(Cl)([Cl:16])(=O)=O>C(Cl)Cl>[Cl:16][CH:8]([S:7][C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)[CH2:9][CH2:10][C:11]#[N:12]

참가 물질

4

반응물 2

HCID 24648Sulfuryl chlorideHCID 2715014-phenylsulfanylbutanenitrile

생성물 1

HCID 13382702HCID 13382702, 화합물수율 102.9%

시약·촉매·용매 1

HCID 6344Dichloromethane용매

실험 절차

To a solution of 50 g (0.28 mole) of 4-phenylthiobutyronitrile in 200 ml of methylene chloride is added 40.5 g (0.3 mole) of sulfuryl chloride dropwise during a period of six hours. Stirring is continued overnight. Solvent and excess sulfuryl chloride is then evaporated under vacuum to give 61 g of a crude product. This material is used in the next experiment without further purification.

후처리

  1. customSolvent and excess sulfuryl chloride is then evaporated under vacuum

출처 및 근거

ORD 기록
ord-c47a004dd6284f2babbf9e21b936bd50
출처 데이터셋
uspto-grants-1987_06
특허 번호
US04675316

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