Toluene → Dimethylammonium 5-(2-Chloro-4-trifluoromethylphenoxy)-2-nitrobenzoate

HRID 65332

반응식

HRID 65332 반응식
[Cl:1][C:2]1[CH:20]=[C:19]([C:21]([F:24])([F:23])[F:22])[CH:18]=[CH:17][C:3]=1[O:4][C:5]1[CH:6]=[CH:7][C:8]([N+:14]([O-:16])=[O:15])=[C:9]([CH:13]=1)[C:10]([OH:12])=[O:11].[C:25]1(C)C=CC=CC=1>>[Cl:1][C:2]1[CH:20]=[C:19]([C:21]([F:22])([F:23])[F:24])[CH:18]=[CH:17][C:3]=1[O:4][C:5]1[CH:6]=[CH:7][C:8]([N+:14]([O-:16])=[O:15])=[C:9]([CH:13]=1)[C:10]([O-:12])=[O:11].[CH3:25][NH2+:14][CH3:8]

참가 물질

3

반응물 2

HCID 1140TolueneHCID 44073Acifluorfen

생성물 1

HCID 21280075Dimethylammonium 5-(2-Chloro-4-trifluoromethylphenoxy)-2-nitrobenzoate

실험 절차

5-(2-Chloro-4-trifluoromethylphenoxy)-2-nitrobenzoic acid (2.0 g) is dissolved in toluene and an excess of anhydrous dimethylamine is bubbled into the reaction mixture, the solvent removed in vacuo and the residue triturated with cold diethyl ether to give 1.1 g of product.

후처리

  1. customan excess of anhydrous dimethylamine is bubbled into the reaction mixture
  2. customthe solvent removed in vacuo
  3. customthe residue triturated with cold diethyl ether

출처 및 근거

ORD 기록
ord-27c9993c0cab40a29c432342e69b7bed
출처 데이터셋
uspto-grants-1986_09
특허 번호
US04613360

연결된 노트

불러오는 중…