Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
3-Chloro-2-methyl-1-propene → Et3SiCH2CHMeCH2Cl
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 3-Chloro-2-methyl-1-propene | HCID 11241 | — |
| 반응물 | Triethylsilane | HCID 12052 | — |
| 반응물 | Trichlorosilane | HCID 24811 | — |
| 생성물 | Et3SiCH2CHMeCH2Cl | HCID 13765477 | 82.5% |
반응 단계
In a 100 ml apparatus, there were combined 11.6 g (0.1 mol) of Et3SiH, 13.6 g (0.1 mol) of Cl3SiH, and 9.1 g of methallyl chloride, followed by addition of 0.05 ml Pt catalyst solution at 21° C. There was a rapid and exothermic reaction to 61° C. in 2 min. Reaction appeared to have stopped and was heated to reflux over 4 hrs. when VPC showed complete reaction. Vacuum distillation yielded 17.03 g (82.5%) of Et3SiCH2CHMeCH2Cl, indicating that Cl3SiH is an effective promoter for the reaction of Et3SiH with methallyl chloride.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04614812 |
| 출처 데이터셋 | uspto-grants-1986_09 |
| ORD ID | ord-f39d2b08875149bdb1d257b2845989f0 |
| 출처 메모 | uspto-grants-1986_09 |