참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Methyldichlorosilane | HCID 6376 | — |
| 반응물 | Allyl chloride | HCID 7850 | — |
| 반응물 | Chlorodimethylsilane | HCID 66108 | — |
| 생성물 | 3-Chloropropyldichloromethylsilane | HCID 82235 | 31.3% |
| 생성물 | Silane, chloro(3-chloropropyl)dimethyl- | HCID 82765 | 22.6% |
반응 단계
In a 100 ml apparatus, there were combined 8.6 g (0.075 mol) of MeSiHCl2, 7.1 g (0.075 mol) of Me2SiHCl, and 5.7 g (0.075 mol) of allyl chloride. Pt catalyst solution (0.01 ml) was added at 37° C., followed by heating up to 45° C. over 1 hr. Vacuum distillation yielded 31.3% of MeSiCl2CH2CH2CH2Cl and 22.6% of Me2SiClCH2CH2CH2Cl. This example shows that neither Me2SiHCl nor MeSiHCl2 is a very effective promoter at the equimolar level for reactions of the other with allyl chloride.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US04614812 |
|---|
| 출처 데이터셋 | uspto-grants-1986_09 |
|---|
| ORD ID | ord-446b3378e7ba490e872ef321e5d44e04 |
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| 출처 메모 | uspto-grants-1986_09 |
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