참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | 3-Chloro-1-butene | HCID 11242 | — |
| 반응물 | Triethylsilane | HCID 12052 | — |
| 생성물 | Chlorotriethylsilane | HCID 13819 | 58.9% |
| 생성물 | Et3SiCH2CH2CHMeCl | HCID 13765479 | 7.6% |
반응 단계
In a 50 ml apparatus, there were combined 4.5 g (0.039 mol) of Et3SiH and 3.5 g (0.039 mol) of 3-chloro-1-butene. Pt catalyst solution (0.01 ml) was added at 22° C., followed by heating up to 77° C. over 70 min. Vacuum distillation yielded 3.46 g (58.9%) of Et3SiCl and 0.61 g (7.6%) of Et3SiCH2CH2CHMeCl. This example demonstrates the low yield of Et3SiCH2CH2CHMeCl from the unpromoted reaction of Et3SiH with 3-chloro-1-butene.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US04614812 |
|---|
| 출처 데이터셋 | uspto-grants-1986_09 |
|---|
| ORD ID | ord-45673193f8e042e78e06b4e60f4b1eb9 |
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| 출처 메모 | uspto-grants-1986_09 |
|---|
