2-Methylbenzenesulfonic acid → 4-(Nonylthio)phenol

HRID 65567

반응식

HRID 65567 반응식
[SH:1][C:2]1[CH:7]=[CH:6][C:5]([OH:8])=[CH:4][CH:3]=1.C1(C)C(S(O)(=O)=O)=CC=CC=1.[CH2:20]=[CH:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28].C([O-])([O-])=O.[Na+].[Na+]>>[CH2:20]([S:1][C:2]1[CH:7]=[CH:6][C:5]([OH:8])=[CH:4][CH:3]=1)[CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28]

참가 물질

5

반응물 4

HCID 69252-Methylbenzenesulfonic acidHCID 10340Sodium CarbonateHCID 312851-NoneneHCID 2401474-Mercaptophenol

생성물 1

HCID 156101604-(Nonylthio)phenol

실험 절차

A 4-(nonylthio)phenol was prepared as follows. 63 Grams of 4-mercaptophenol and 5 grams of toluene sulfonic acid were heated to 60° C. Then 76 grams of nonene (approximately 55 percent 2,4-di-methyl-1-heptene) were added over a 38 minute period. The flask contents were neutralized with 5 grams of Na2CO3 in aqueous solution, decanted and stripped to a pot temperature of 180° C. at 26 millimeters of mercury. The product weighed 113 grams.

후처리

  1. customdecanted
  2. customstripped to a pot temperature of 180° C. at 26 millimeters of mercury

출처 및 근거

ORD 기록
ord-32a0201ad0a74ba9ad771ca02bcf4f95
출처 데이터셋
uspto-grants-1978_12
특허 번호
US04128530

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