38263-46-6 → HCID 55300761, 화합물

HRID 656253노트

반응식

HRID 656253 반응식
[C@H:1]12[O:7][C@H:4]([CH:5]=[CH:6]1)[CH2:3][C@H:2]2[C:8]([OH:10])=[O:9]>C(O)C.[Pd]>[C@H:1]12[O:7][C@@H:4]([CH2:5][CH2:6]1)[CH2:3][C@H:2]2[C:8]([OH:10])=[O:9]

참가 물질

4

반응물 1

HCID 983398038263-46-6

생성물 1

HCID 55300761HCID 55300761, 화합물

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 702Ethanol용매

실험 절차

A solution of 1 mmol of (1S,2R,4S)-7-oxabicyclo[2.2.1]-hept-5-ene-2-carboxylic acid [185840-15-7] in 30 ml of ethanol is hydrogenated in the presence of 0.150 g of Pd/C 10% at room temperature until conversion is complete. The reaction mixture is clarified by filtration, and the filtrate is evaporated. The title compound is obtained from the residue by flash chromatography (SiO2 60 F).

후처리

  1. filtrationThe reaction mixture is clarified by filtration
  2. customthe filtrate is evaporated

출처 및 근거

ORD 기록
ord-04eaa553a8774abab23d4618f0b453fb
출처 데이터셋
uspto-grants-2011_12
특허 번호
US08071651B2

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