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2-Hydroxyethyl acrylate → 2-Hydroxyethyl acrylate dodecyl acrylate

HRID 65657
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HRID 65657 반응식
[C:1]([O:5][CH2:6][CH2:7][OH:8])(=[O:4])[CH:2]=[CH2:3].[C:9]([O:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])(=[O:12])[CH:10]=[CH2:11]>C(C(C)=O)C.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>[C:1]([O:5][CH2:6][CH2:7][OH:8])(=[O:4])[CH:2]=[CH2:3].[C:9]([O:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])(=[O:12])[CH:10]=[CH2:11]
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참가 물질

5

반응물 2

HCID 131652-Hydroxyethyl acrylateHCID 75084Lauryl acrylate

생성물 1

HCID 227574042-Hydroxyethyl acrylate dodecyl acrylate수율 95%

시약·촉매·용매 2

HCID 7187Benzoyl Peroxide촉매HCID 6569Methyl Ethyl Ketone용매

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온도
80 °C

실험 절차

11.6 gm (0.1 mole) of 2-hydroxyethyl acrylate and 144 gm (0.6 mole) of dodecyl acrylate were dissolved in 360 gm of methyl ethyl ketone. To the solution obtained were added 3.1 gm of dibenzoyl peroxide as a catalyst. The reaction mixture was maintained for 5 hours under stirring at a temperature of 80° C. After the reaction was completed, the solvent was distilled off and the reaction product was washed several times with methanol. 148 gm, (95% of theory) of 2-hydroxyethyl acrylate/dodecyl acrylate copolymer (1:6 molar ratio) were obtained.

후처리

  1. customTo the solution obtained
  2. temperatureThe reaction mixture was maintained for 5 hours
  3. distillationthe solvent was distilled off
  4. washthe reaction product was washed several times with methanol

출처 및 근거

ORD 기록
ord-2bbc4b23c5c64a3ab005af79ef0409da
출처 데이터셋
uspto-grants-1978_12
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US04128635

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