참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Sodium Fluoride | HCID 5235 | — |
| 반응물 | CF3(CF2)9Ocf(CF3)CF2ococf(CF3)ocf2CF2CF3 | HCID 131723952 | — |
| 생성물 | CF3(CF2)9Ocf(CF3)cof | HCID 85777200 | 63.8% |
반응 단계
CF3(CF2)9OCF(CF3)CF2OCOCF(CF3)OCF2CF2CF3 (2.0 g) obtained in Example 23 was charged into a flask together with a NaF powder (0.05 g) and heated at 150° C. for 24 hours in an oil bath with vigorous stirring. At an upper part of the flask, a reflux condenser adjusted to a temperature of 20° C., was installed. After cooling, the liquid sample (1.9 g) was recovered. By GC-MS, it was confirmed that CF3CF(OCF2CF2CF3)COF and the above-identified compound were the main products. The yield was 63.8%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US07083705B2 |
|---|
| 출처 데이터셋 | uspto-grants-2006_08 |
|---|
| ORD ID | ord-c7929215a1044905b53af2ac9d1a111e |
|---|
| 출처 메모 | uspto-grants-2006_08 |
|---|
