Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Acetonitrile → Ranisen
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Acetonitrile | HCID 6342 | — |
| 반응물 | 1,1-Bis(methylthio)-2-nitroethylene | HCID 83623 | — |
| 반응물 | 5-(((2-Aminoethyl)thio)methyl)-N,N-dimethyl-2-furanmethanamine | HCID 162203 | — |
| 생성물 | Ranisen | HCID 5039 | — |
반응 단계
2-[[[5-(Dimethylamino)methyl-2-furanyl]methyl]thio]ethanamine (4.25 g) and 1,1-bis(methylthio)-2-nitroethene (3.3 g) were refluxed in acetonitrile (50 ml) for 14 hr. Solvent was removed and the residue dissolved in 36% methanolic methylamine (50 ml) and the solution refluxed for 8 hr. Solvents were removed and the residue in methanol treated with charcoal. Filtration and evaporation of the solvent gave the title compound as Example 15 (5.0 g).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04128658 |
| 출처 데이터셋 | uspto-grants-1978_12 |
| ORD ID | ord-590ae28d589b41ae960292662b4c4b89 |
| 출처 메모 | uspto-grants-1978_12 |