Isovanillin → 3-((tert-Butyldimethylsilyl)oxy)-4-methoxybenzaldehyde

HRID 658761노트

반응식

HRID 658761 반응식
[OH:1][C:2]1[CH:3]=[C:4]([CH:7]=[CH:8][C:9]=1[O:10][CH3:11])[CH:5]=[O:6].[C:12]([Si:16](Cl)([CH3:18])[CH3:17])([CH3:15])([CH3:14])[CH3:13]>>[Si:16]([O:1][C:2]1[CH:3]=[C:4]([CH:7]=[CH:8][C:9]=1[O:10][CH3:11])[CH:5]=[O:6])([C:12]([CH3:15])([CH3:14])[CH3:13])([CH3:18])[CH3:17]

참가 물질

3

반응물 2

HCID 12127IsovanillinHCID 28928tert-Butyldimethylsilyl chloride

생성물 1

HCID 3595583-((tert-Butyldimethylsilyl)oxy)-4-methoxybenzaldehyde수율 100%

실험 절차

Prepared as in Example 12-1c from 3-hydroxy-4-methoxybenzaldehyde and tert-butylchlorodimethylsilane. Yield 100%, yellowish liquid. MS 267 (MH+).

출처 및 근거

ORD 기록
ord-e48f70dc59ff4fdda07a021aee6fabac
출처 데이터셋
uspto-grants-2011_12
특허 번호
US08076491B2

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