3,5-Di-tert-butylcatechol → 3,5-Di-tert-butyl-1,2-benzoquinone
반응식
[C:1]([C:5]1[CH:11]=[C:10]([C:12]([CH3:15])([CH3:14])[CH3:13])[CH:9]=[C:7]([OH:8])[C:6]=1[OH:16])([CH3:4])([CH3:3])[CH3:2]>[Ag]=O.CCOCC>[C:1]([C:5]1[C:6](=[O:16])[C:7](=[O:8])[CH:9]=[C:10]([C:12]([CH3:15])([CH3:14])[CH3:13])[CH:11]=1)([CH3:4])([CH3:2])[CH3:3]참가 물질
4
실험 절차
To a solution of 5 g. (22.5 mmol.) of 3,5-di-t-butylcatechol in 75 ml. of ether at 0° was added 25 g. of silver oxide. The reaction mixture was stirred at 0° for 30 minutes then at ambient temperature for an additional 30 minutes. The mixture was filtered and the filtrate was evaporated to dryness. Benzene was added to the residue and the resulting precipitate was collected by filtration and air dried to give 3,5-di-t-butyl-1,2-dioxobenzene, m.p. 110-112°.
후처리
- waitat ambient temperature for an additional 30 minutes
- filtrationThe mixture was filtered
- customthe filtrate was evaporated to dryness
- additionBenzene was added to the residue
- filtrationthe resulting precipitate was collected by filtration and air
- customdried
출처 및 근거
- ORD 기록
- ord-0fae10ee2f394bb092bc579c7f50e561
- 출처 데이터셋
- uspto-grants-1978_12
- 특허 번호
- US04131734
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