Pentaerythritol → Pentaerythritol Tetrakis(2,4-dimethoxybenzoate)

HRID 66691

반응식

HRID 66691 반응식
[CH3:1][O:2][C:3]1[CH:11]=[C:10]([O:12][CH3:13])[CH:9]=[CH:8][C:4]=1[C:5](Cl)=[O:6].[OH:14][CH2:15][C:16]([CH2:21][OH:22])([CH2:19][OH:20])[CH2:17][OH:18]>>[CH3:1][O:2][C:3]1[CH:11]=[C:10]([O:12][CH3:13])[CH:9]=[CH:8][C:4]=1[C:5]([O:14][CH2:15][C:16]([CH2:21][O:22][C:5](=[O:6])[C:4]1[CH:8]=[CH:9][C:10]([O:12][CH3:13])=[CH:11][C:3]=1[O:2][CH3:1])([CH2:19][O:20][C:5](=[O:6])[C:4]1[CH:8]=[CH:9][C:10]([O:12][CH3:13])=[CH:11][C:3]=1[O:2][CH3:1])[CH2:17][O:18][C:5](=[O:6])[C:4]1[CH:8]=[CH:9][C:10]([O:12][CH3:13])=[CH:11][C:3]=1[O:2][CH3:1])=[O:6]

참가 물질

3

반응물 2

HCID 8285PentaerythritolHCID 27347192,4-Dimethoxybenzoyl chloride

생성물 1

HCID 20530744Pentaerythritol Tetrakis(2,4-dimethoxybenzoate)수율 78%

실험 절차

Using the procedure of Eample I, 2,4-dimethoxybenzoyl chloride was allowed to react with pentaerythritol in the molar ratio of 4:1. The reaction gave a 78% yield of white crystalline product having a melting point of 125°-126.5° C. and the infrared spectrum was a consistent with the expected tetraester with no hydroxyl band and an ester carbonyl band at 5.85μ (s).

출처 및 근거

ORD 기록
ord-42dfaebc9cba4c71a19c8c1f54691fa8
출처 데이터셋
uspto-grants-1982_08
특허 번호
US04342875

연결된 노트

불러오는 중…