Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
tert-BUTYL CHLORIDE → Di-tert-butyldichlorostannane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | tert-BUTYL CHLORIDE | HCID 10486 | — |
| 반응물 | Tin tetrachloride | HCID 24287 | — |
| 반응물 | Magnesium Chloride | HCID 5360315 | — |
| 반응물 | Magnesium | HCID 5462224 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 용매 | Heptane | HCID 8900 | — |
| 생성물 | Di-tert-butyldichlorostannane | HCID 88053 | — |
반응 단계
The Grignard reagent from t-butyl chloride (92.5 g., 1 mole), magnesium (24.3 g., 1 mole) and tetrahydrofuran (11.) was added dropwise to a solution of tin(iv) chloride (104 g., 0.4 mole) in heptane (11.). A vigorous reaction started at once and magnesium chloride precipitated. After completion of the addition, the mixture was refluxed for 4 hrs. Cooling and work-up gave a yellow oil. This was distilled to give the desired product as a clear oil which solidified readily (70.0 g., 58%), m.p. 42°-43° (lit., 142°); b.p. 66°/3 mm.; n.m.4. 81.45(s).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04343815 |
| 출처 데이터셋 | uspto-grants-1982_08 |
| ORD ID | ord-237d128ed39c4c0eb2170263a11b92e5 |
| 출처 메모 | uspto-grants-1982_08 |