Bromotriphenylmethane → 1-Bromo-4,4-dimethyl-3-triphenylmethoxy-trans-1-octene

HRID 67020

반응식

HRID 67020 반응식
[Br:1]/[CH:2]=[CH:3]/[CH:4]([OH:12])[C:5]([CH3:11])([CH3:10])[CH2:6][CH2:7][CH2:8][CH3:9].[C:13]1([C:19](Br)([C:26]2[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=2)[C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1>>[Br:1]/[CH:2]=[CH:3]/[CH:4]([O:12][C:19]([C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)([C:26]1[CH:27]=[CH:28][CH:29]=[CH:30][CH:31]=1)[C:20]1[CH:21]=[CH:22][CH:23]=[CH:24][CH:25]=1)[C:5]([CH3:11])([CH3:10])[CH2:6][CH2:7][CH2:8][CH3:9]

참가 물질

3

반응물 2

HCID 11692BromotriphenylmethaneHCID 204656241-Bromo-4,4-dimethyl-trans-1-octen-3-ol

생성물 1

HCID 204656911-Bromo-4,4-dimethyl-3-triphenylmethoxy-trans-1-octene

실험 절차

Treatment of 1.88 g. (8 moles) of 1-bromo-4,4-dimethyl-trans-1-octen-3-ol (Example 1174) with 2.58 g. (8 moles) of triphenylmethyl bromide in 20 ml. of pyridine and purification of Florisil®, all as described in Example 728 gives the title compound.

후처리

  1. customof pyridine and purification of Florisil®

출처 및 근거

ORD 기록
ord-973692436fc84fc28af69c5c4a0929da
출처 데이터셋
uspto-grants-1982_08
특허 번호
US04343949

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