Bromine → 1-Bromo-3-triphenylmethoxy-trans-1-nonene

HRID 67026

반응식

HRID 67026 반응식
[C:1]1([C:7]([C:24]2[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=2)([C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)[O:8][CH:9]([CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17])[C:10]#[CH:11])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C(BC(C(C)C)C)(C(C)C)C.[Br:41]Br>>[Br:41]/[CH:11]=[CH:10]/[CH:9]([O:8][C:7]([C:1]1[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1)([C:18]1[CH:19]=[CH:20][CH:21]=[CH:22][CH:23]=1)[C:24]1[CH:25]=[CH:26][CH:27]=[CH:28][CH:29]=1)[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17]

참가 물질

4

반응물 3

HCID 24408BromineHCID 192733Bis(1,2-dimethylpropyl)boraneHCID 204657223-Triphenylmethoxy-1-nonyne

생성물 1

HCID 204655201-Bromo-3-triphenylmethoxy-trans-1-nonene

실험 절차

Treatment of 3-triphenylmethoxy-1-nonyne (Example 128) with disiamylborane and the bromine by the procedure described in Example 1173 is productive of the title compound.

출처 및 근거

ORD 기록
ord-9a4274936f6441fe8affb6c22beeffe7
출처 데이터셋
uspto-grants-1982_08
특허 번호
US04343949

연결된 노트

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