2-Tolyl isocyanate → Benzenamine, N,N'-methanetetraylbis(2-methyl-

HRID 67035

반응식

HRID 67035 반응식
[C:1]1([CH3:10])[C:2]([N:7]=[C:8]=O)=[CH:3][CH:4]=[CH:5][CH:6]=1>C(=O)=O>[C:1]1([CH3:10])[CH:6]=[CH:5][CH:4]=[CH:3][C:2]=1[N:7]=[C:8]=[N:7][C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][C:1]=1[CH3:10]

참가 물질

3

반응물 1

HCID 691942-Tolyl isocyanate

생성물 1

HCID 102025Benzenamine, N,N'-methanetetraylbis(2-methyl-수율 85.8%

시약·촉매·용매 1

HCID 280Carbon Dioxide용매

실험 절차

133 g of o-tolylisocyanate and 5 g of solid, insoluble catalyst from Example 1a were heated together to 180° C. with stirring. After the evolution of 12.3 liters of carbon dioxide, which took place within 1.5 hours, the catalyst was suction filtered and the filtrate distilled. 95.3 g of di-o-tolyl-carbodiimide, b.p. 135°-137° C./0.1 Torr were obtained (87% of the theory).

후처리

  1. customwithin 1.5 hours
  2. filtrationfiltered
  3. distillationthe filtrate distilled

출처 및 근거

ORD 기록
ord-85c2942e9f2541e99cc5825fb232fb2c
출처 데이터셋
uspto-grants-1982_08
특허 번호
US04344855

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