Benzene, 1-bromo-3-iodo- → 3-(3-Bromophenyl)phenanthrene

반응식

BrC1C=CC([C:8]2[CH:21]=[CH:20][C:19]3[C:18]4[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=4)[CH:12]=[CH:11][C:10]=3[CH:9]=2)=CC=1.C1C2C=CC3C(=CC=CC=3)C=2C=C(B(O)O)C=1.[Br:39][C:40]1[CH:41]=[C:42](I)[CH:43]=[CH:44][CH:45]=1>>[Br:39][C:40]1[CH:45]=[C:44]([C:10]2[CH:11]=[CH:12][C:21]3[CH:20]=[CH:19][C:18]4[C:17]([C:8]=3[CH:9]=2)=[CH:16][CH:15]=[CH:14][CH:13]=4)[CH:43]=[CH:42][CH:41]=1

참가 물질

반응물 3

HCID 11561Benzene, 1-bromo-3-iodo-

HCID 46835783Phenanthren-3-ylboronic acid

HCID 581942352-(4-Bromophenyl)phenanthrene

생성물 1

HCID 581941693-(3-Bromophenyl)phenanthrene

실험 절차

Synthesis was performed in the same manner as in the synthesis of 2-(4-bromophenyl)phenanthrene except that: phenanthrene-3-boronic acid was used instead of phenanthrene-2-boronic acid; and 3-bromoiodobenzene was used instead of 4-bromoiodobenzene.

후처리

customSynthesis

출처 및 근거

ORD 기록: ord-4ee5fc5885d24de5a6b7b43811796b04
출처 데이터셋: uspto-grants-2014_09
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08822041B2

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