참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Acetate | HCID 175 | — |
| 반응물 | Tetradecylphenol | HCID 116800 | — |
| 반응물 | Aluminum(III) Chloride | HCID 6451240 | — |
| 용매 | Chloroform | HCID 6212 | — |
| 생성물 | 1-(2-Hydroxy-5-tetradecylphenyl)ethanone | HCID 14256205 | — |
반응 단계
A 900 mg portion of 4-tetradecylphenol, acetate was heated at 70° C. under argon and 720 mg of aluminum trichloride was added portionwise. After 2 hours the temperature was raised to 120° C. and the mixture was heated at this temperature for 45 minutes. The mixture was then cooled, diluted with chloroform, washed with 50% aqueous hydrochloric acid then water and dried. The solvents were removed and the residue recrystallized from ethermethanol, giving 850 mg of the desired compound, mp 38.5°-39.5° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US04981989 |
|---|
| 출처 데이터셋 | uspto-grants-1991_01 |
|---|
| ORD ID | ord-8491a99218094883bf7e595ecb6b0aee |
|---|
| 출처 메모 | uspto-grants-1991_01 |
|---|
