Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Triphenylphosphine → HCID 178453006, 화합물
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Triphenylphosphine | HCID 11776 | — |
| 반응물 | 2-Amino-4-chlorobenzenethiol | HCID 12000 | — |
| 반응물 | Di-tert-butyl diazene-1,2-dicarboxylate | HCID 6034084 | — |
| 반응물 | HCID 178453005 | HCID 178453005 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | HCID 178453006 | HCID 178453006 | — |
반응 단계
A solution of tert-butyl (5-(hydroxymethyl)-4H-1,2,4-triazol-3-yl)carbamate (190 mg, 0.888 mmol), 2-amino-4-chlorobenzenethiol (213 mg, 1.332 mmol), PPh3 (466 mg, 1.776 mmol) and di-tert-butylazodicarboxylate (409 mg, 1.776 mmol) in CH2Cl2 (10 ml) was stirred at room temperature for 2 days. The solvent was then removed and the crude residues was loaded on silica gel column to get the title compound.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08822530B2 |
| 출처 데이터셋 | uspto-grants-2014_09 |
| ORD ID | ord-26e7f3bb0d004fe48de4f7eeeebe439b |
| 출처 메모 | uspto-grants-2014_09 |