1-Bromo-4-(trimethoxymethyl)benzene → 1-(4-Bromophenyl)-4-t-butyl-2,6-dioxa-7-thiabicyclo[2,2,2]octane

반응식

[OH:1][CH2:2][C:3]([CH2:10][OH:11])([C:6]([CH3:9])([CH3:8])[CH3:7])[CH2:4][SH:5].CO[C:14](OC)(OC)[C:15]1[CH:20]=[CH:19][C:18]([Br:21])=[CH:17][CH:16]=1>>[Br:21][C:18]1[CH:19]=[CH:20][C:15]([C:14]23[S:5][CH2:4][C:3]([C:6]([CH3:7])([CH3:8])[CH3:9])([CH2:10][O:11]2)[CH2:2][O:1]3)=[CH:16][CH:17]=1

참가 물질

반응물 2

HCID 135812791-Bromo-4-(trimethoxymethyl)benzene

HCID 19373362HCID 19373362, 화합물

생성물 1

HCID 200755551-(4-Bromophenyl)-4-t-butyl-2,6-dioxa-7-thiabicyclo[2,2,2]octane

실험 절차

From 2,2-di-hydroxymethyl-3,3-dimethyl-butan-1-thiol and trimethyl 4-bromo-orthobenzoate, trimethyl 4-chloro-orthobenzoate, trimethyl orthocyclohexylcarboxylate and trimethyl ortho-cycloheptylcarboxylate in the manner described previously, the following compounds were prepared:

후처리

customthe following compounds were prepared

출처 및 근거

ORD 기록: ord-02819a222c84480d8746b7e2611a3ae6
출처 데이터셋: uspto-grants-1991_01
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04985582

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