endo-Dicyclopentadiene → Dicyclopentadiene

HRID 70723

반응식

HRID 70723 반응식
[CH2:1]1[CH:5]2[C@@H:6]3[CH:10]=[CH:9][C@H:8]([CH:4]2[CH:3]=[CH:2]1)[CH2:7]3>Cl[Ru](=CC1C=CC=CC=1)([P](C1CCCCC1)(C1CCCCC1)C1CCCCC1)([P](C1CCCCC1)(C1CCCCC1)C1CCCCC1)Cl>[CH2:1]1[CH:5]2[CH:6]3[CH:10]=[CH:9][CH:8]([CH:4]2[CH:3]=[CH:2]1)[CH2:7]3

참가 물질

3

반응물 1

HCID 15618652endo-Dicyclopentadiene2회

생성물 1

HCID 6492Dicyclopentadiene

시약·촉매·용매 1

HCID 178479819HCID 178479819, 화합물촉매

실험 절차

Grubbs catalyst containing MCs (approximately 1 mg) were dispersed in neat DCPD (100 mg). The MCs were ruptured with a laser or by physical crushing. After rupturing, a gel was produced in approximately 10-30 minutes, with formation of a rubbery state, and then a solid resin over time. No gelling of DCPD was evident over two weeks with uncrushed MCs; however, the latent catalyst remained active as subsequent rupture of the MCs that had been left for five days still produced a gel in approximately 45-60 minutes. A background gelling rate of approximately 1 day was obtained with prepared particles that were not free flowing.

후처리

  1. customa gel was produced in approximately 10-30 minutes, with formation of a rubbery state
  2. customstill produced a gel in approximately 45-60 minutes
  3. customrate of approximately 1 day
  4. customwas obtained with prepared particles that

출처 및 근거

ORD 기록
ord-28128eb9393442438c449ae2b9ebcc04
출처 데이터셋
uspto-grants-2014_09
특허 번호
US08822618B2

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