Methylpropanediol → 2-(3-Hydroxy-2-methylpropoxy)-6-nitrobenzonitrile

HRID 711865

반응식

[CH3:1][CH:2]([CH2:5][OH:6])[CH2:3][OH:4].[N+:7]([C:10]1[CH:17]=[CH:16][CH:15]=[C:14]([N+]([O-])=O)[C:11]=1[C:12]#[N:13])([O-:9])=[O:8]>>[OH:4][CH2:3][CH:2]([CH3:1])[CH2:5][O:6][C:14]1[CH:15]=[CH:16][CH:17]=[C:10]([N+:7]([O-:9])=[O:8])[C:11]=1[C:12]#[N:13]

참가 물질

반응물 2

HCID 75103Methylpropanediol

HCID 520718Dinitrobenzonitrile

생성물 1

HCID 673988582-(3-Hydroxy-2-methylpropoxy)-6-nitrobenzonitrile수율 37%

실험 절차

Prepared as in Example 215c from 2-methylpropane-1,3-diol and 2,6-dinitrobenzonitrile in 37% yield. MS 237 (MH+).

출처 및 근거

ORD 기록: ord-ba736e29883340f38509d7bba1dc03d2
출처 데이터셋: uspto-grants-2015_11
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US09181276B2

연결된 노트

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