Methanol → Methyl 5-amino-o-anisate
반응식
[OH:1][C:2]1[CH:11]=[CH:10][C:9]([N+:12]([O-])=O)=[CH:8][C:3]=1[C:4]([O:6][CH3:7])=[O:5].[O-]S([O-])(=O)=O.[Na+].[Na+].[CH3:22]O>[Pd]>[NH2:12][C:9]1[CH:10]=[CH:11][C:2]([O:1][CH3:22])=[C:3]([CH:8]=1)[C:4]([O:6][CH3:7])=[O:5]참가 물질
5
실험 절차
The hydrogenation of methyl 2-hydroxy-5-nitrobenzoate (700 mg, 3.3 mmol) using 10% Pd—C (100 mg) and Na2SO4 (100 mg) in MeOH at 50 psi gave methyl 5-amino-2-methoxybenzoate (600 mg).
출처 및 근거
- ORD 기록
- ord-08efbd127163432e91321c6abd1742e6
- 출처 데이터셋
- uspto-grants-2014_09
- 특허 번호
- US08822685B2
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