Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
6-Methyl-5-hepten-2-one → (3,7-Dimethylocta-2,6-dienyl)benzene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 6-Methyl-5-hepten-2-one | HCID 9862 | — |
| 반응물 | Phenethyltriphenylphosphonium bromide | HCID 10863251 | — |
| 반응물 | Butyllithium | HCID 178418339 | — |
| 생성물 | (3,7-Dimethylocta-2,6-dienyl)benzene | HCID 317701 | 17.4% |
반응 단계
Starting from phenethyltriphenylphosphonium bromide (3.48 g, 7.78 mmol, 1.0 equiv.), n-BuLi (1.6 M in hexanes, 4.9 mL, 7.78 mmol, 1.0 equiv.) and 6-methylhept-5-en-2-one (1.48 g, 11.7 mmol, 1.5 equiv.), 0.29 g (17%) of the title compound as a colorless oil was obtained after purification by flash chromatography on SiO2 (cyclohexane).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US09193935B2 |
| 출처 데이터셋 | uspto-grants-2015_11 |
| ORD ID | ord-98f93d6b988d4c6b80eea9dbff336a80 |
| 출처 메모 | uspto-grants-2015_11 |