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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 718515생성일: 2026년 10월 27일

6-Methyl-5-hepten-2-one → (3,7-Dimethylocta-2,6-dienyl)benzene

https://huagongshe.com/reaction/718515

반응식

참여 물질

역할이름HCID투입량
반응물6-Methyl-5-hepten-2-oneHCID 9862—
반응물Phenethyltriphenylphosphonium bromideHCID 10863251—
반응물ButyllithiumHCID 178418339—
생성물(3,7-Dimethylocta-2,6-dienyl)benzeneHCID 31770117.4%

반응 단계

Starting from phenethyltriphenylphosphonium bromide (3.48 g, 7.78 mmol, 1.0 equiv.), n-BuLi (1.6 M in hexanes, 4.9 mL, 7.78 mmol, 1.0 equiv.) and 6-methylhept-5-en-2-one (1.48 g, 11.7 mmol, 1.5 equiv.), 0.29 g (17%) of the title compound as a colorless oil was obtained after purification by flash chromatography on SiO2 (cyclohexane).

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US09193935B2
출처 데이터셋uspto-grants-2015_11
ORD IDord-98f93d6b988d4c6b80eea9dbff336a80
출처 메모uspto-grants-2015_11