참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Potassium Carbonate | HCID 11430 | — |
| 반응물 | Iodobenzene | HCID 11575 | — |
| 반응물 | 3,5-Bis(1,1-dimethylethyl)-2-hydroxybenzoic acid | HCID 88208 | — |
| 반응물 | Sodium Bisulfite | HCID 23665763 | — |
| 반응물 | 12,12-Dimethyl-10,12-dihydroindeno[2,1-b]carbazole | HCID 86685012 | — |
| 촉매 | Copper | HCID 23978 | — |
| 용매 | Dodecylbenzene | HCID 31237 | — |
| 생성물 | 12,12-Dimethyl-10-phenyl-10,12-dihydroindeno[2,1-b]carbazole | HCID 86685014 | 88.3% |
반응 단계
The resulting 12,12-dimethyl-10,12-dihydroindeno[2,1-b]carbazole (7.8 g), iodobenzene (3.7 ml), sodium bisulfite (0.43 g), a copper powder (0.17 g), 3,5-di(tert-butyl)salicylic acid (0.69 g), potassium carbonate (5.71 g), and dodecylbenzene (10 ml) were added to a nitrogen-substituted reaction vessel, heated, and stirred at 170° C. for 10 hours. The mixture was cooled to 100° C., extracted by adding toluene (100 ml), concentrated under reduced pressure, and crystallized using n-hexane (30 ml) to obtain a pale yellow powder of 12,12-dimethyl-10-phenyl-10,12-dihydroindeno[2,1-b]carbazole (8.73 g; yield 88.3%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US09196837B2 |
|---|
| 출처 데이터셋 | uspto-grants-2015_11 |
|---|
| ORD ID | ord-e750f15685eb4227a37c2a101453df7e |
|---|
| 출처 메모 | uspto-grants-2015_11 |
|---|
