Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Dimethylformamide → 7-Bromo-12,12-dimethyl-10-phenyl-10,12-dihydroindeno[2,1-b]carbazole
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Dimethylformamide | HCID 6228 | — |
| 반응물 | N-bromobutanimide | HCID 67184 | — |
| 반응물 | 12,12-Dimethyl-10-phenyl-10,12-dihydroindeno[2,1-b]carbazole | HCID 86685014 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | 7-Bromo-12,12-dimethyl-10-phenyl-10,12-dihydroindeno[2,1-b]carbazole | HCID 86685015 | 94.8% |
반응 단계
The resulting 12,12-dimethyl-10-phenyl-10,12-dihydroindeno[2,1-b]carbazole (7.5 g) and DMF (53 ml) were added to a reaction vessel. N-bromosuccinimide (3.72 g) was added under ice-cooled conditions, and the mixture was stirred for 9 hours and then left for one night. Water (260 ml) was added, and the mixture was subjected to filtration to obtain a brownish white powder of 7-bromo-12,12-dimethyl-10-phenyl-10,12-dihydroindeno[2,1-b]carbazole (8.67 g; yield 94.6%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US09196837B2 |
| 출처 데이터셋 | uspto-grants-2015_11 |
| ORD ID | ord-482225d7960242e497efc6bf60ca73fc |
| 출처 메모 | uspto-grants-2015_11 |