Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 719052생성일: 2026년 10월 26일
Dimethylformamide → 10-(Biphenyl-4-yl)-7-bromo-12,12-dimethyl-10,12-dihydroindeno[2,1-b]carbazole
https://huagongshe.com/reaction/719052
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Dimethylformamide | HCID 6228 | — |
| 반응물 | N-bromobutanimide | HCID 67184 | — |
| 반응물 | 10-(Biphenyl-4-yl)-12,12-dimethyl-10,12-dihydroindeno[2,1-b]carbazole | HCID 86685016 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | 10-(Biphenyl-4-yl)-7-bromo-12,12-dimethyl-10,12-dihydroindeno[2,1-b]carbazole | HCID 86685017 | 69.5% |
반응 단계
The resulting 10-(biphenyl-4-yl)-12,12-dimethyl-10,12-dihydroindeno[2,1-b]carbazole (42.5 g) and DMF (2.5 L) were added to a reaction vessel, and the mixture was heated up to 70° C. and dissolved. After cooled to a room temperature, N-bromo-succinimide (17.4 g) was added, and the mixture was stirred for 7 hours. Water (2.5 L) was added, and filtration was performed to obtain a white powder of 10-(biphenyl-4-yl)-7-bromo-12,12-dimethyl-10,12-dihydroindeno[2,1-b]carbazole (34.9 g; yield 69.5%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US09196837B2 |
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| 출처 데이터셋 | uspto-grants-2015_11 |
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| ORD ID | ord-b49c04135a1f43248579297398a18285 |
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| 출처 메모 | uspto-grants-2015_11 |
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