Triethyl Phosphate → HCID 178476992, 화합물

HRID 72070

반응식

HRID 72070 반응식
[P:1]([O:9]CC)([O:6][CH2:7][CH3:8])([O:3][CH2:4][CH3:5])=[O:2].COC(=O)[O-].[CH2:17]([N+:19]1[CH:23]=[CH:22][N:21]([CH3:24])[CH:20]=1)[CH3:18]>CO>[CH2:4]([O:3][P:1]([O-:9])([O:6][CH2:7][CH3:8])=[O:2])[CH3:5].[CH2:17]([N+:19]1[CH:23]=[CH:22][N:21]([CH3:24])[CH:20]=1)[CH3:18]

참가 물질

4

반응물 2

HCID 6535Triethyl PhosphateHCID 178462724HCID 178462724, 화합물

생성물 1

HCID 178476992HCID 178476992, 화합물

시약·촉매·용매 1

HCID 887Methanol용매2회

실험 절차

By adding 50 parts of triethyl phosphate (TEP: produced by Daihachi Chemical Industries Co., Ltd.) to the methanol solution of 50 parts of 1-ethyl-3-methylimidazolium methyl carbonate salt obtained in Production Example 7 and carrying out a salt exchange reaction, there was obtained a methanol solution of 1-ethyl-3-methylimidazolium diethyl phosphate monoanion. The above-described solution was heated under reduced pressure of 1.0 kPa or less at 50° C. to distill methanol until no distillate of methanol was observed. Thereafter, the temperature was raised from 50° C. to 100° C. and heating was continued for 30 minutes to distill and remove monomethyl carbonate (HOCO2CH3), methanol, and carbon dioxide (slight amounts of methanol and carbon dioxide are formed by thermal decomposition of monomethyl carbonate. Hereinafter, these are abbreviated as by-products). Thus, 1-ethyl-3-methylimidazolium diethyl phosphate monoanion, electrolyte (C-4), was obtained. The yield was 99 parts (yield based on the weight of 50 parts of 1-ethyl-3-methylimidazolium methyl carbonate salt; hereinafter the same shall apply). The molecular weight of the electrolyte (C-4) was 266.

후처리

  1. customobtained in Production Example 7
  2. customa salt exchange reaction

출처 및 근거

ORD 기록
ord-faeb4cd3df6541a0b67462c6707d7b27
출처 데이터셋
uspto-grants-2014_09
특허 번호
US08828261B2

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