Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Methacryloyl chloride → 5,5,5-Trifluoro-4-hydroxy-4-(trifluoromethyl)pentan-2-yl methacrylate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Methacryloyl chloride | HCID 13528 | — |
| 반응물 | Methacrylate | HCID 87595 | — |
| 반응물 | 1,1,1-Trifluoro-2-(trifluoromethyl)-2,4-pentanediol | HCID 118191 | — |
| 반응물 | Butyllithium | HCID 178418339 | — |
| 생성물 | 5,5,5-Trifluoro-4-hydroxy-4-(trifluoromethyl)pentan-2-yl methacrylate | HCID 16050138 | — |
반응 단계
The title compound was prepared in the same fashion as the above described methacrylate using 142 g (0.63 mol) of 1,1,1-trifluoro-2-trifluoromethyl-2,4-pentanediol, 793 mL (1.27 mol) of n-butyllithium (1.6 M in hexane) and 73 g (0.69 mol) of methacryloyl chloride to yield, after distillation at 67° C. at 1.0 mm Hg, 142 g (76%) of the 2° methacrylate as a clear, colorless oil.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07135595B2 |
| 출처 데이터셋 | uspto-grants-2006_11 |
| ORD ID | ord-c60a7d4659984f9bbb8d0556806e196d |
| 출처 메모 | uspto-grants-2006_11 |