Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
4-Bromoanisole → 1,1'-Biphenyl, 4,4'-dimethoxy-
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 4-Bromoanisole | HCID 7730 | — |
| 반응물 | (4-Methoxyphenyl)boronic acid | HCID 201262 | — |
| 생성물 | 1,1'-Biphenyl, 4,4'-dimethoxy- | HCID 16484 | 87% |
반응 단계
From 4-methoxy-bromobenzene and 4-methoxyphenyl boronic acid, yield 87%; mp 178-180° C. (lit.,1 179-180° C.); IR: 1599, 1493, 1466 and 1290; 1H NMR (400 MHz; CDCl3): 7.47 (4H, d, J 8.7), 6.96 (4H, d, J 8) and 3.84 (6H, s); 13C NMR (CDCl3): 159.1, 133.9, 128.1, 114.5 and 55.7; m/z (EI) 214 (100%, M+), 171 (70), 128 (50) and 69 (40)(Found: M+, 214.099. C14H14O2 requires M, 214.099).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08828902B2 |
| 출처 데이터셋 | uspto-grants-2014_09 |
| ORD ID | ord-5098d817417d43229234288d64586902 |
| 출처 메모 | uspto-grants-2014_09 |