Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1-Bromo-4-nitrobenzene → 4-Methoxy-4'-nitrobiphenyl
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1-Bromo-4-nitrobenzene | HCID 11466 | — |
| 반응물 | (4-Methoxyphenyl)boronic acid | HCID 201262 | — |
| 생성물 | 4-Methoxy-4'-nitrobiphenyl | HCID 11128079 | 91% |
반응 단계
From 4-nitro-bromobenzene and 4-methoxyphenyl boronic acid, yield 91%; mp 104-105° C. (lit.,3 106-107° C.); IR: 1597, 1509, 1342 and 125I; 1H NMR (600 MHz; CDCl3): 8.27 (2H, d, J 9), 7.69 (2H, d, J 8.4), 7.58 (2H, d, J 9), 7.02 (2H, d, J 8.4) and 3.87 (3 H, s); 13C NMR (CDCl3): 160.4, 147.1, 146.5, 131, 128.5, 127, 124.1, 114.6 and 55.4; m/z (EI) 229 (25%, M+), 169. (30), 131 (30) and 69 (100)(Found: M+, 229.073. C13H11NO3 requires M, 184.074).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08828902B2 |
| 출처 데이터셋 | uspto-grants-2014_09 |
| ORD ID | ord-abd08cf4e519411992d4959947452920 |
| 출처 메모 | uspto-grants-2014_09 |