Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
4-Bromoanisole → 1-(4'-Methoxy(1,1'-biphenyl)-4-yl)ethanone
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 4-Bromoanisole | HCID 7730 | — |
| 반응물 | 4-Acetylphenylboronic acid | HCID 3702122 | — |
| 생성물 | 1-(4'-Methoxy(1,1'-biphenyl)-4-yl)ethanone | HCID 301557 | 84% |
반응 단계
From 4-methoxy-bromobenzene and 4-acetylphenyl boronic acid, yield 84%; mp 150-151° C. (lit.,5 153-154° C.); IR: 1676, 1602, 1456 and 1236; 1H NMR (400 MHz; CDCl3): 8.01 (2H, d, J 8.4), 7.64 (2H, d, J 8.3), 7.58 (2H, d, J 8.8), 7 (2H, d, J 8.5), 3.86 (3H, s) and 2.62 (3H, s); 13C NMR (CDCl3): 197.6, 159.9, 145.3, 135.3, 132.2, 128.9, 128.3, 126.5, 114.4, 55.3 and 26.5; m/z (EI) 226 (80%, M+), 211 (100) and 69 (60)(Found: M+, 226.099. C15H14O2 requires M, 226.099).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08828902B2 |
| 출처 데이터셋 | uspto-grants-2014_09 |
| ORD ID | ord-835e09acd3e34d54ad32b448e5dc62c0 |
| 출처 메모 | uspto-grants-2014_09 |