Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1-Bromo-4-nitrobenzene → Ethanone, 1-(4'-nitro[1,1'-biphenyl]-4-yl)-
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1-Bromo-4-nitrobenzene | HCID 11466 | — |
| 반응물 | 4-Acetylphenylboronic acid | HCID 3702122 | — |
| 생성물 | Ethanone, 1-(4'-nitro[1,1'-biphenyl]-4-yl)- | HCID 8676 | 97% |
반응 단계
From 4-nitro-bromobenzene and 4-acetylphenyl boronic acid, yield 97%; mp 144-146° C. (lit.,7 150-151° C.); IR: 1681, 1530, 1497, 1361 and 1280; 1H NMR (400 MHz; CDCl3): 8.02 (2H, d, J 8.5), 7.64-7.56 (4H, m), 7.16 (2H, t, J 8.5) and 2.63 (3H, s); 13C NMR (CDCl3): 197.5, 164.2, 144.7, 136, 128.9, 127, 116, 115.7 and 26.6; m/z (EI) 199 (30%, M+−C2H2O), 131 (50) and 69 (100)(Found: M+−C2H2O, 199.062).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08828902B2 |
| 출처 데이터셋 | uspto-grants-2014_09 |
| ORD ID | ord-333ac6e4e9aa4208bd8f5b2a462024ad |
| 출처 메모 | uspto-grants-2014_09 |