1-Bromo-4-nitrobenzene → 4-Nitro-1,1'-biphenyl

HRID 72093

반응식

HRID 72093 반응식
[N+:1]([C:4]1[CH:9]=[CH:8][C:7](Br)=[CH:6][CH:5]=1)([O-:3])=[O:2].[C:11]1(B(O)O)[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1>>[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)=[CH:6][CH:5]=1)([O-:3])=[O:2]

참가 물질

3

반응물 2

HCID 114661-Bromo-4-nitrobenzeneHCID 66827Phenylboronic Acid

생성물 1

HCID 71144-Nitro-1,1'-biphenyl

실험 절차

4-Nitro-bromobenzene and phenyl boronic acid were reacted as described in Example 6. The catalyst was recovered by filtration, washed and dried (as described in Example 1). This process was then repeated 4 times with fresh reagents and the recycled catalyst. The yields of isolated 4-Nitrobiphenyl were as follows:

후처리

  1. filtrationThe catalyst was recovered by filtration
  2. washwashed
  3. customdried (as described in Example 1)

출처 및 근거

ORD 기록
ord-05b04c0b57cb4631982c99303f558e8c
출처 데이터셋
uspto-grants-2014_09
특허 번호
US08828902B2

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