Trimellitic acid → HCID 21884599, 화합물

HRID 722623

반응식

[NH2:1][C:2]1[CH:3]=[C:4]([C:9]2[O:10][C:11]3[CH:17]=[CH:16][C:15]([C:18]4[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=4)=[CH:14][C:12]=3[N:13]=2)[CH:5]=[CH:6][C:7]=1[Cl:8].[C:24]1([C:36](O)=[O:37])[C:25]([C:33](O)=[O:34])=[CH:26][C:27]([C:30]([OH:32])=[O:31])=[CH:28][CH:29]=1>>[Cl:8][C:7]1[CH:6]=[CH:5][C:4]([C:9]2[O:10][C:11]3[CH:17]=[CH:16][C:15]([C:18]4[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=4)=[CH:14][C:12]=3[N:13]=2)=[CH:3][C:2]=1[N:1]1[C:33](=[O:34])[C:25]2[C:24](=[CH:29][CH:28]=[C:27]([C:30]([OH:32])=[O:31])[CH:26]=2)[C:36]1=[O:37]

참가 물질

반응물 2

HCID 10708Trimellitic acid

HCID 21884362HCID 21884362, 화합물

생성물 1

HCID 21884599HCID 21884599, 화합물

실험 절차

Prepared by the method of Example 15e), from 2-(3-amino-4-chlorophenyl)-5-phenylbenzoxazole (43 mg, 0.13 mmol) and 1,2,4-benzenetricarboxylic acid (26 mg, 0.13 mmol) the title compound was obtained (10 mg, 15%). 1H NMR (DMSO) δ 8.58(d, 1H), 8.48(dd, 1H), 8.38(m, 2H), 8.17(d, 1H), 8.08(d, 1H), 7.99(d, 1H), 7.88(d, 1H), 7.76(m, 3H), 7.50(m, 2H), 7.39(t, 1H). MS 492.8 m/z (M−H)−.

출처 및 근거

ORD 기록: ord-36fdc0c9e5e045cea4a077148275810f
출처 데이터셋: uspto-grants-2006_11
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US07138425B2

연결된 노트

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