N,N,N'-trimethyl-N'-(4-nitrophenyl)-1,2-ethanediamine → N-(2-Dimethylaminoethyl)-N-methylbenzene-1,4-diamine

반응식

[CH3:1][N:2]([CH3:16])[CH2:3][CH2:4][N:5]([CH3:15])[C:6]1[CH:11]=[CH:10][C:9]([N+:12]([O-])=O)=[CH:8][CH:7]=1>[Zn]>[CH3:1][N:2]([CH3:16])[CH2:3][CH2:4][N:5]([CH3:15])[C:6]1[CH:11]=[CH:10][C:9]([NH2:12])=[CH:8][CH:7]=1

참가 물질

실험 절차

The compound was prepared by zinc dust reduction of N,N,N′-trimethyl-N′-(4-nitrophenyl)ethane-1,2-diamine in analogy to the method in example 3. The product with the molecular weight of 193.29 (C11H19N3); MS (ESI): 194 ([M+H]+), was obtained in this way.

후처리

customMS (ESI): 194 ([M+H]+), was obtained in this way

출처 및 근거

ORD 기록: ord-31bccd887b124b24bf2f233545e19fbf
출처 데이터셋: uspto-grants-2006_11
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US07141561B2

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참가 물질

반응물 1

HCID 21873305N,N,N'-trimethyl-N'-(4-nitrophenyl)-1,2-ethanediamine

생성물 1

HCID 21873395N-(2-Dimethylaminoethyl)-N-methylbenzene-1,4-diamine

시약·촉매·용매 1

HCID 23994Zinc촉매

실험 절차

후처리

customMS (ESI): 194 ([M+H]+), was obtained in this way

출처 및 근거

ORD 기록: ord-31bccd887b124b24bf2f233545e19fbf
출처 데이터셋: uspto-grants-2006_11
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US07141561B2

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불러오는 중…