Dimethylformamide → N,N,N'-trimethyl-N'-(4-nitrophenyl)-1,2-ethanediamine
반응식
[CH3:1][N:2]([CH3:7])[CH2:3][CH2:4][NH:5][CH3:6].C(=O)([O-])[O-].[K+].[K+].[N+:14]([C:17]1[CH:22]=[CH:21][C:20](F)=[CH:19][CH:18]=1)([O-:16])=[O:15].CN(C)C=O>O>[CH3:1][N:2]([CH3:7])[CH2:3][CH2:4][N:5]([CH3:6])[C:20]1[CH:21]=[CH:22][C:17]([N+:14]([O-:16])=[O:15])=[CH:18][CH:19]=1참가 물질
6
실험 절차
A mixture of N,N,N′-trimethylethane-1,2-diamine (2.17 g), potassium carbonate (3.0 g), 4-nitrofluorobenzene and dimethylformamide (30 ml) was stirred for 72 hours. The reaction mixture was diluted with water and extracted with ethyl acetate. The organic phase was washed with water and saturated brine, dried and concentrated. The product with the molecular weight of 223.28 (C11H17N3O2); MS (ESI): 224 ([M+H]+), was obtained in this way.
후처리
- extractionextracted with ethyl acetate
- washThe organic phase was washed with water and saturated brine
- customdried
- concentrationconcentrated
- customMS (ESI): 224 ([M+H]+), was obtained in this way
출처 및 근거
- ORD 기록
- ord-d79caca2d30e429c984791767474afae
- 출처 데이터셋
- uspto-grants-2006_11
- 특허 번호
- US07141561B2
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