Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
O-Phenylenediamine → 2(1H)-Quinoxalinone, 3-(3,4-dihydroxy-5-nitrophenyl)-
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | O-Phenylenediamine | HCID 7243 | — |
| 반응물 | Benzeneacetic acid, 3,4-dihydroxy-5-nitro-alpha-oxo-, hexyl ester | HCID 5747978 | — |
| 용매 | Methanol | HCID 887 | — |
| 생성물 | 2(1H)-Quinoxalinone, 3-(3,4-dihydroxy-5-nitrophenyl)- | HCID 135665317 | — |
반응 단계
A mixture of 396.0 mg of n-hexyl 3,4-dihydroxy-5-nitrophenylglyoxylate and 137.6 mg of 1,2-phenylenediamine is heated to 120° for 60 minutes. Thereafter, the mixture is suspended in methanol, filtered under suction and recrystallized from N,N-dimethylformamide/water. There is obtained 3-(3,4-dihydroxy-5-nitrophenyl)-2(1H)-quinoxalinone of m.p. >300°.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05705703 |
| 출처 데이터셋 | uspto-grants-1998_01 |
| ORD ID | ord-556a763f96064bb89e9a20c5cf7ad195 |
| 출처 메모 | uspto-grants-1998_01 |