Ethyl Acetate → HCID 19707473, 화합물
반응식
[O:1]([C:8]1[CH:15]=[CH:14][C:11]([CH:12]=O)=[CH:10][CH:9]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[Li][CH2:17][CH2:18][CH2:19][CH3:20].C(OCC)(=[O:23])C.C([O-])(O)=O.[Na+]>C1COCC1.CCCCCC>[OH:23][CH2:17][CH2:18][CH2:19][CH2:20][CH2:12][C:11]1[CH:14]=[CH:15][C:8]([O:1][C:2]2[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=2)=[CH:9][CH:10]=1참가 물질
7
실험 절차
To a solution of 4-phenoxybenzaldehyde (704 mg, 3.56 mmol) in 15 mL of THF at -78° C. was added n-BuLi dropwise (3.73 mmol, 2.5M in hexane). After 24 hours, the reaction was poured into ethyl acetate and sat. aq. NaHCO3 solution, then washed with brine, dried (Na2SO4) and concentrated in vacuo to provide the crude product.
후처리
- washwashed with brine
- dry with materialdried (Na2SO4)
- concentrationconcentrated in vacuo
출처 및 근거
- ORD 기록
- ord-0b16357306bf43d9bafdbd5422b3dd0e
- 출처 데이터셋
- uspto-grants-1998_01
- 특허 번호
- US05710171
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