Ethanol → HCID 178454912, 화합물

HRID 729159노트

반응식

HRID 729159 반응식
C(OC([P:9]([CH2:14][CH2:15][CH2:16][CH3:17])(=[O:13])[O:10][CH2:11][CH3:12])(OCC)C)C.C(O)C.C[Si](C)(C)Cl>ClCCl>[CH2:14]([PH:9](=[O:13])[O:10][CH2:11][CH3:12])[CH2:15][CH2:16][CH3:17]

참가 물질

5

반응물 3

HCID 702EthanolHCID 6397ChlorotrimethylsilaneHCID 19090884Ethyl butyl(1,1-diethoxyethyl)phosphinate

생성물 1

HCID 178454912HCID 178454912, 화합물

시약·촉매·용매 1

HCID 6344Dichloromethane용매

실험 절차

A solution of 176 g of ethyl 1,1-diethoxyethyl(n-butyl)phosphinate in 540 ml of absolute dichloromethane containing 10% of absolute ethanol is treated with 143.6 g of trimethylchlorosilane. After stirring for 48 hoursat room temperature, the solvent is removed in vacuo to afford a pale yellow oil. Distillation in vacuo affords ethyl n-butyl-phosphinate, b.p. 27°-34° (2×10-2 mbar).

후처리

  1. customthe solvent is removed in vacuo
  2. customto afford a pale yellow oil
  3. distillationDistillation in vacuo

출처 및 근거

ORD 기록
ord-a8cbfe325ab74ddfb78df72e06aa8af7
출처 데이터셋
uspto-grants-1991_09
특허 번호
US05051524

반응 노트

불러오는 중…