참여 물질
| 역할 | 이름 | HCID | 투입량 |
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| 반응물 | Tridecanoic acid | HCID 12530 | — |
| 반응물 | Cadmium Oxide | HCID 10197697 | — |
| 생성물 | Cadmium dodecylcarboxylate | HCID 87682535 | — |
반응 단계
Cadmium oxide (0.127 g, 1 mmol) and dodecylcarboxylic acid (0.500 g) were reacted at 220° C. for 10 min, cooled to 90° C., then a cadmium dodecylcarboxylate (precursor) was formed. Into said system, toluene (10 ml), trioctylphosphine oxide (3.866 g) and trioctylphosphine (3.7 g) were added. Then a 0.05M aqueous solution of sodium sulfide (10 ml) was added. After the system was reacted at 90° C. for 3 h, a clear yellow sol containing CdS nanoparticles was obtained. Said sol has a typical exciton absorption peak of the CdS nanoparticles, can result in a quantum size effect and emit a fairly strong blue light under the irradiation of a UV lamp.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 특허 번호 | US07582543B2 |
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| 출처 데이터셋 | uspto-grants-2009_09 |
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| ORD ID | ord-74af6909199943a096b166cbbab97075 |
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| 출처 메모 | uspto-grants-2009_09 |
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