Isoamyl Nitrite → HCID 53419315, 화합물
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N[C:2]1[C:6]([C:7]([O:9][CH2:10][CH3:11])=[O:8])=[CH:5][N:4]([C:12]2[CH:17]=[CH:16][CH:15]=[C:14]([Br:18])[CH:13]=2)[N:3]=1.C(ON=O)CC(C)C>C1COCC1>[CH2:10]([O:9][C:7]([C:6]1[CH:2]=[N:3][N:4]([C:12]2[CH:17]=[CH:16][CH:15]=[C:14]([Br:18])[CH:13]=2)[CH:5]=1)=[O:8])[CH3:11]참가 물질
4
실험 절차
To a solution of the ester from Step 1 (0.5 g, 1.61 mmol) in THF (4.3 mL) was added isoamylnitrite (0.434 mL, 3.23 mmol), and the mixture was refluxed for 16 hours. It was cooled to room temperature, concentrated, dried and used as such for the subsequent step without any purification.
후처리
- temperaturethe mixture was refluxed for 16 hours
- concentrationconcentrated
- customdried
- customwithout any purification
출처 및 근거
- ORD 기록
- ord-37887dfd4d7249bfaa4acf1cd72e031b
- 출처 데이터셋
- uspto-grants-2009_09
- 특허 번호
- US07589116B2
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