2-(4-Trimethylsilanylethynylphenoxy)ethanol → 2-(4-Ethynylphenoxy)ethan-1-ol
반응식
C[Si]([C:5]#[C:6][C:7]1[CH:16]=[CH:15][C:10]([O:11][CH2:12][CH2:13][OH:14])=[CH:9][CH:8]=1)(C)C>CCOC(C)=O>[C:6]([C:7]1[CH:16]=[CH:15][C:10]([O:11][CH2:12][CH2:13][OH:14])=[CH:9][CH:8]=1)#[CH:5]참가 물질
3
실험 절차
The product was obtained analogously to Example 1.1c starting from 12.20 g (52.05 mmol) of 2-(4-trimethylsilanylethynylphenoxy)ethanol. Yield: 7.70 g (91% of theoretical); C1oH10O2 (M=162.185); calc.: molpeak (M+H)+: 163; found: molpeak (M+H)+: 163; Rf value: 0.32 (silica gel, PE/EtOAc 6:4).
후처리
- customThe product was obtained analogously to Example 1.1c
출처 및 근거
- ORD 기록
- ord-b9bf8cfa3087477f85ba7aa4218b9f46
- 출처 데이터셋
- uspto-grants-2009_09
- 특허 번호
- US07592358B2
반응 노트
불러오는 중…